Original Articles Publications

Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts

Date:2009-09-28

S. Ito, K. Munakata, A. Nakamura, K. Nozaki*
J. Am. Chem. Soc. 2009, 131, 14606–14607.  DOI: 10.1021/ja9050839

Abstract: Coordination copolymerization of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain −CH2CH(OAc)− units, has been accomplished using novel palladium complexes bearing alkylphosphine−sulfonate ligands.

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