Original Articles Publications

Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene


S. Ito, M. Kanazawa, K. Munakata, J. Kuroda, Y. Okumura, K. Nozaki*
J. Am. Chem. Soc. 2011, 133, 1232–1235.  DOI: 10.1021/ja1092216

Abstract: Coordination−insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine−sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain −CH2CH(CH2FG)− units.

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